Download e-book for kindle: Physical Surfaces by J.J. Bikerman (Eds.)

By J.J. Bikerman (Eds.)

ISBN-10: 0120978512

ISBN-13: 9780120978519

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Nauk Ukr. SSR. 5, No. 2, 50 (1965). Yu. V. Naidich and I. A. , Akad. Nauk Ukr. SSR. 5, No. 10, 61 (1965). 44 CHAPTER II Physical Chemistry of Liquid Surfaces EFFECT OF THE GAS PHASE O N SURFACE TENSION §26. The tension γ acting in the interface between two phases naturally de­ pends on the nature of both. However, when " surface tension of liquid A " is mentioned, only one phase is specified. Generally speaking, it is implied that the gas phase is the vapor of A saturated at the temperature of the ex­ periment.

This result is valid also when the contact angles right and left have any finite values. In this case, the horizontal force exerted by the surface tension of the curved menis­ cus is wy sin Θ. At the same time, h = \2y\{g{p — Pi)](l — sin 0), because cos φ of Eq. (14) is equal to sin 0, so that W = wy(\ — sin Θ). The force on a vertical wall is wy whatever the magnitude of Θ. This conclusion is experimentally confirmed by the suitability of the fourth method for differential measurement of y (see §20).

This reduced temperature corresponds to 7°C for diethyl ether, to 49° for chloro­ form, and to 115° for water. 9 g/sec . The products p J T\ , if p is in 10 g/cm · sec , are respectively, 84, 116, and 313. 37. Obviously, the agree­ ment with the theory is only semiquantitative. The classical theory of the corresponding states cannot be expected to be valid at very low temperatures at which quantum effects become prominent. However, it is still not clear how Eq. (8) and analogous rules should be altered to conform with the theory of q u a n t a .

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Physical Surfaces by J.J. Bikerman (Eds.)


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