By Marina A. Petrukhina, Lawrence T. Scott, Harold W. Kroto
This e-book is the 1st of its kind to mirror upon the intense and swiftly growing to be curiosity in open geodesic polyaromatic molecules, particularly targeting their synthesis and reactivity in steel binding reactions. The e-book greatly covers all features concerning the fullerene fragment chemistry: present artificial ideas, description of the to be had contributors of this new kinfolk (which has grown to more than two dozens contributors, without any being on hand commercially), molecular geometry and traits within the sturdy country packing, in addition to extensions into actual homes and new buckybowl-based molecules and fabrics. It covers basic learn concerning a brand new type of hydrocarbons, particularly open geodesic polyarenes that map onto the surfaces of fullerenes (and known as fullerene fragments or buckybowls.
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Additional resources for Fragments of Fullerenes and Carbon Nanotubes: Designed Synthesis, Unusual Reactions, and Coordination Chemistry
Chakrabarti, K. Ruud, J. Phys. Chem. A 2009, 113, 5485---5488. CHAPTER 2 SYNTHESIS OF BOWL-SHAPED AND BASKET-SHAPED FULLERENE FRAGMENTS VIA BENZANNULATED ENYNE---ALLENES KUNG K. WANG, HU CUI, and BO WEN 2-1. 1,2 In the cases where an aryl substituent is also present at the allenic terminus, an intramolecular radical---radical coupling reaction through a carbon---carbon double bond of the aryl substituent at the allenic terminus could occur, leading to the corresponding Diels---Alder adducts as depicted in 3.
A) C. D. Sherrill, T. Takatani, E. G. Hohenstein, J. Phys. Chem. A 2009, 113, 10146---10159; (b) K. E. Riley, M. Pitonak, J. Cerny, P. Hobza, J. Chem. Theory Comput. 2010, 6, 66---80. 40 MOLECULAR CLIPS AND TWEEZERS WITH CORANNULENE PINCERS 61. (a) P. Hobza, H. L. Selzle, E. W. Schlag, J. Phys. Chem. 1996, 100, 18790---18794; (b) V. Sˇpirko, O. Enkvist, P. Soldan, H. L. Selzle, E. W. Schlag, P. Hobza, J. Chem. Phys. 1999, 111, 572---582. 62. F. R. Fronczek, A. Sygula, unpublished results. 63. L.
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Fragments of Fullerenes and Carbon Nanotubes: Designed Synthesis, Unusual Reactions, and Coordination Chemistry by Marina A. Petrukhina, Lawrence T. Scott, Harold W. Kroto